CH 475: INORGANIC CHEMISTRY

Structure & Bonding

Block 5, 2005-6

Keith Kester & Ted Lindeman

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Week 1
Week 2
Week 3+
M.O. Diagram

Week 3+ Schedule

Mon. Feb. 6: 
Written exam over Vincent and Miessler & Tarr, Chapter 4.

Tue. Feb. 7: 9:00 am: 

READING:
Miessler & Tarr, Chapter 5, Sections 5-4-7 & 5-5. (Recommended exercises 5-8 & 5-9.) Miessler & Tarr, Chapter 7, Section 7-3 (Recommended exercise 7-5).
                                             AND
Handouts:"Hybrid Orbitals in Light of Atomic Electron Configuration and VSEPR Theory;" "The Band Theory"

8:30 am Class: Barnes 143: Wrap up on Molecular Orbital Theory; and exploration of its application to metal and semiconductor and insulator bonding.

12:30 pm Lab




Wed. Feb. 8: 9:00 am:
 

M.O. Exercise 

Valence Bond (localized orbitals) AND M.O. Description for NO2 (derived using group theory) and (optionally) the Generating Orbital approach due.


Thur. Feb. 9: 

READING:  Douglas, McDaniel & Alexander, Concepts and Models of Inorganic Chemistry, Chapter 6, "Inorganic Solids," pp. 194-220.
                                           AND 
Handouts: "Bond-Type Triangles"(in the Packet) & "Packing Structure Exercises"
Optional: Computer Software in Mac Computer Classroom: CrystalDesigner and Lattice Maker..

8:30 am Class - In-class activities: “Inorganic Solids,” Parts A & B (Note B.4 is in preparation for the Integrative Project, Part B.)

12:30 pm Lab

Optional Computer Assignment: Do the Tutorial - CaTiO3 in CrystalDesigner on the computers in the MAC section of the Keck Lab.

Fri. Feb. 10:
 

READING: Douglas et. al., Chapter 6, pp. 220-251; 
Recommended Problems for Douglas, Chapter 6: 1,6,8,13,15,18,24,26,29.

8:30 am Class - In-class activities in “Inorganic Solids,” Part C.

1:00 pm: Structure and Bonding description of magnetite due.


Mon. Feb. 13: 

A.M.: Consultation time with Professors Kester & Lindeman

12:30 - 3:30 pm: Oral Exams

Tue. Feb. 14:  

8:30 - 9:45 am:  Consultation time with Professors Kester & Lindeman

10:00 am - 12:00 noon:  Oral Exams

1:15 - 4:15 pm:  Oral Exams


Wed. Feb. 15:  

9:30 - 11:30 am:  Oral Exams

12 Noon:  Lab books, Integrative Project, Course Reflections, Comment on Objectives met and not met, Learning Aid Evaluation, Course Evaluation, and written evaluation of oral exam due.